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trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene CAS NO.54125-02-9
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Keywords
- trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene
- Tetraisopropyl methylenediphosphonate
- ALDRICH
Quick Details
- ProName: trans-1-Methoxy-3-trimethylsiloxy-1,3-...
- CasNo: 54125-02-9
- Molecular Formula: (CH3)3SiOC(=CH2)CH=CHOCH3
- Application: trans-1-Methoxy-3-trimethylsiloxy-1,3-...
- PackAge: 1, 5 g in ampule
- Purity: 95%
- LimitNum: 0
Superiority
trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene. Mukaiyama-Michael-type addition/heterocyclization of trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky?s diene) with 1,2-diaza-1,3-butadiene has been investigated. Asymmetric hetero-Diels-Alder cyclization of Danishefsky?s diene with benzaldehyde catalyzed by mesoporous inorganic/metalorganic hybrid materials has been reported.
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