Germany
(Trimethylsilyl)isothiocyanate CAS NO.2290-65-5
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Keywords
- (Trimethylsilyl)isothiocyanate
- Isothiocyanatotrimethylsilane
- ALDRICH
Quick Details
- ProName: (Trimethylsilyl)isothiocyanate
- CasNo: 2290-65-5
- Molecular Formula: (CH3)3SiNCS
- Application: Trimethylsilyl isothiocyanate was used...
- PackAge: 10, 50 g in glass bottle
- Purity: 99%
- LimitNum: 0
Superiority
Trimethylsilyl isothiocyanate (TMS-ITC) reacts with fullerene-mixed peroxide C60(O)(OOtBu)4 to yield isothiocyanate derivative C60(NCS)(OH)(OOtBu)4. TMS-ITC undergoes condensation with ethyl 2-benzylamino-5-methyl-3-phenylcyclopent-1-enecarboxylate to yield 1-benzyl-5-methyl-7-phenyl-2-thioxo-1,2,3,5,6,7-hexahydrocyclopentapyrimidin-4-one. It participates in ring opening reaction of N-substituted aziridines and cyclohexene oxide.
Details
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![(2R,4aR,6S,7R,8S,8aR)-7,8-bis(Benzyloxy)-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine](http://file1.lookchem.com/300w/substances/2022-02-14-05/743c9c1a-8170-44e0-b8d3-9d03985e814d.png)
![(2S,4aR,6S,7R,8S,8aS)-2-Phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine-7,8-diyl dibenzoate](http://file1.lookchem.com/300w/substances/2022-02-21-07/cce0fbe9-6220-45ed-aa58-f13a601529c8.png)
![(2R,4aR,6S,7R,8S,8aR)-2-Phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine-7,8-diyl dibenzoate](http://file1.lookchem.com/300w/substances/2022-02-24-07/84712a3c-6054-46a2-82b9-b478a500cdca.png)
![(2R,4aR,6R,7S,8R,8aS)-2-Phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine-7,8-diol](http://file1.lookchem.com/cas/reactions/2021/07/13/6935579.png)