Germany
1-Acetoxy-1,3-butadiene CAS NO.1515-76-0
- Min.Order: 0
- Payment Terms:
- Product Details
Keywords
- 1-Acetoxy-1,3-butadiene
- 1,3-Butadienyl acetate
- ALDRICH
Quick Details
- ProName: 1-Acetoxy-1,3-butadiene
- CasNo: 1515-76-0
- Molecular Formula: CH2=CHCH=CHOCOCH3
- Application: 1-Acetoxy-1,3-butadiene was used as di...
- PackAge: 10 g in glass bottle
- Purity: mixture of cis and trans
- LimitNum: 0
Superiority
1-Acetoxy-1,3-butadiene (1-ABD) can be generated by potassium or sodium acetate catalyzed reaction between crotonaldehyde and acetic anhydride. The product is a mixture of cis and trans forms, that has been confirmed by its physical properties and IR spectra. It is reported to be formed as a major product during the acetoxylation of 1,3-butadiene (BD) in gas-phase in the presence of Pd-KOAc (palladium-potassium acetate) catalyst. 1-ABD participates as 2? or 4? diene in cycloaddition reactions. Enantioselective Diels Alder reaction of 2-methoxy-5-methyl-1,4-benzoquinone with 1-ABD in the presence of molecular sieves (mesh size:4?) has been reported.
Details
#
![(2R,4aR,6S,7R,8S,8aR)-7,8-bis(Benzyloxy)-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine](http://file1.lookchem.com/300w/substances/2022-02-14-05/743c9c1a-8170-44e0-b8d3-9d03985e814d.png)
![(2S,4aR,6S,7R,8S,8aS)-2-Phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine-7,8-diyl dibenzoate](http://file1.lookchem.com/300w/substances/2022-02-21-07/cce0fbe9-6220-45ed-aa58-f13a601529c8.png)
![(2R,4aR,6S,7R,8S,8aR)-2-Phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine-7,8-diyl dibenzoate](http://file1.lookchem.com/300w/substances/2022-02-24-07/84712a3c-6054-46a2-82b9-b478a500cdca.png)
![(2R,4aR,6R,7S,8R,8aS)-2-Phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxine-7,8-diol](http://file1.lookchem.com/cas/reactions/2021/07/13/6935579.png)